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Oxidation Numbers and Redox Reactions

  • Rules for Assigning Oxidation Numbers

1). Oxidation state of Free elements is  0 e.g. Li, H2, C etc

2). Oxidation state monatomic ion is the charge Na+ = +1, Mg2+ = +2, etc

3). Oxidation state of O is -2 in all its compounds exceptions:
a.  peroxides e.g. Na2O2; Na-O-O-Na; H2O2; H-O-O-H  where Oxygens ox. # = -1
b. superoxides e.g. KO2 where ox. # = -1/2

4). H is +1 in all its compounds exceptions metal hydrides then = -1 e.g. NaH or MgH2

5). F is - 1 in all its compounds except in elemental form then ox. # is 0..

6). Alkali metals are always +1; Alkaline Earths are always +2.

7). Sum of oxidation states is zero for neutral compounds, and equal to the overall charge for polyatomic ions.

Questions

Highlight to Reveal Answers
What is the oxidation number for Pb in PbO2 ?+4
What is the oxidation number for Cl in HClO3 ?+5
What is the oxidation number for Cl in ClO2 ?+4
What is the oxidation number for H in H2 ?0
What is the oxidation number for F in FeS ?+2
What is the oxidation number for C in C60 ?0
What is the oxidation number for Sn in Sn2+ ?+2
What is the oxidation number for S in SO22- ?+2
What is the oxidation number for Mg in MgO ?+2
What is the oxidation number for S in S2O82- ?+7
What is the oxidation number for Fe in Fe(OH)3 ?+3
What is the oxidation number for Cl in ClO2- ?+3
What is the oxidation number for C in CO2 ?+4
What is the oxidation number for Ag in AgCl ?+1
What is the oxidation number for Ga in GaN ?+3
What is the oxidation number for Al in Al2O3 ?+3
What is the oxidation number for P in H3PO3 ?+3
What is the oxidation number for C in CF4 ?+4
What is the oxidation number for P in P2O5 ?+5
What is the oxidation number for O in H2O ?-2
What is the oxidation number for F in FeS ?+2
What is the oxidation number for As in AsO2- ?+3
What is the oxidation number for Mn in MnO4- ?+7
What is the oxidation number for Sb in Sb2O5 ?+5
What is the oxidation number for Fe in Mg3(FeCl6)2 ?+3
What is the oxidation number for Hg in HgO ?+2
What is the oxidation number for O in H2O2 ?-1
What is the oxidation number for C in CN- ?+2
What is the oxidation number for Cl in ClO4- ?+7

Oxidation- the loss of electrons. Look for the oxidation number increasing.  LEO lose electrons oxidation

Reduction- gain of electrons. Look for the oxidation number decreasing.     GER gain electrons reduction

 

Oxidizing Agents are Reactants that cause oxidation by being reduced (losing electrons; ox. # decreases).

Reducing Agents are Reactants that cause reduction by being oxidized (gaining electrons; ox. # increases).

In the above example Cu2+ is the Oxidizing Agent.

In the above example Mg is the Reducing Agents.

Classsify the following as reducing agents or oxidizing agents

Highlight to reveal answer

Cl2+    2Fe2+--> 2Cl-+     2Fe3+
OARA ReactantsONLY
Cu+   2Ag+

--> 

Cu2++2 Ag
RAOA ReactantsONLY

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