Naming Alkanes
1. Name each compound after its longest continuous chain of carbons, using the appropriate prefix. The ending for alkanes is always "-ane".
| Carbon | Compound |
| 1 | Meth |
| 2 | Eth |
| 3 | Prop |
| 4 | But |
| 5 | Penta |
| 6 | Hexa |
| 7 | Hept |
| 8 | Oct |
| 9 | Non |
| 10 | Deca |
| 11 | Undeca |
| 12 | Dodeca |
| 13 | Trideca |
| 14 | Tetradeca |
| 15 | Pentadeca |
2. Number the carbon chain so that the carbons with substituents other than hydrogen will have the lowest possible numbers (***not always left to right).
3. Name the substituents other than hydrogen by the appropriate carbon fragment prefix followed by "-yl". Think of substituents as modifiers taking the adjective ending "-yl", and the carbon backbone as the main idea taking the noun ending -ane. Give a name and carbon-number location for each substituent, ordering the substituents alphabetically. (Other orders besides alphabetical are used.)
4. Prefixes in front of alkyl groups (i.e. di-, tri-, tetra-, penta-...) are used to indicate how many of a particular alkyl group are found in the molecule. There must be one carbon-number location for each alkyl group. Prefixes are ignored in alphabetizing.
5. ALWAYS use a comma between numbers. ALWAYS use a hyphen between a number and a letter.
Common names that you should know (college level) are... Common names that you should know (college level) are...
isobutyl = 2-methylpropyl
sec-butyl = 1-methylpropyl
tert-butyl = 1,1-dimethylethyl
neo-pentyl = 2,2-dimethylpropyl
iso-pentyl = 3-methylbutyl
Flash of Nomenclature of Alkanes