Naming Alkanes

 

 

1. Name each compound after its longest continuous chain of carbons, using the appropriate prefix.  The ending for alkanes is always "-ane". 

Carbon Compound
1 Meth
2 Eth
3 Prop
4 But
5 Penta
6 Hexa
7 Hept
8 Oct
9 Non
10 Deca
11 Undeca
12 Dodeca
13 Trideca
14 Tetradeca
15 Pentadeca

2. Number the carbon chain so that the carbons with substituents other than hydrogen will have the lowest possible numbers (***not always left to right). 

3. Name the substituents other than hydrogen by the appropriate carbon fragment prefix followed by "-yl". Think of substituents as modifiers taking the adjective ending "-yl", and the carbon backbone as the main idea taking the noun ending -ane. Give a name and carbon-number location for each substituent, ordering the substituents alphabetically. (Other orders besides alphabetical are used.)

4. Prefixes in front of alkyl groups (i.e. di-, tri-, tetra-, penta-...) are used to indicate how many of a particular alkyl group are found in the molecule. There must be one carbon-number location for each alkyl group. Prefixes are ignored in alphabetizing.

5. ALWAYS use a comma between numbers. ALWAYS use a hyphen between a number and a letter. 

Alkanes Naming Quiz

Common names that you should know (college level) are... Common names that you should know (college level) are... isopropyl = 1-methylethyl

isobutyl = 2-methylpropyl

sec-butyl = 1-methylpropyl

tert-butyl = 1,1-dimethylethyl

neo-pentyl = 2,2-dimethylpropyl

iso-pentyl = 3-methylbutyl

Flash of Nomenclature of Alkanes

 

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