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Formula, Total & Net Ionic Equations

 Writing Reactions  (Molecular, Ionic and Net Ionic) Equations

This may seem overwhelming, but I broke it down step by step for you.

Read the rules, watch the video, then practice it a few times and it is really not that bad.

Before you do anything, you are going to need 4 lines to do this.

**Top line is for the reaction in word form

**2nd is the Molecular formula equation

**3rd is the Ionic Equation

**4th is the Net Ionic Equation

If you are given just the names of the reactants.   (Click here if you have formulas)

(1 page printable PDF of these steps)
 Silver Chloride + Rubidium Nitrate Lead (II) Nitrate + Sodium Phosphate

The Steps

1. On line 1...Write these and the names of products by switching last names of the reactants

2. Check solubility of the products, to determine if there is a reaction.  If there is no reaction...STOP!!!!!

(You do not want to do all this work if there is no reaction.)

3. On line 3...If there is a solid, liquid or gas formed,  write each of the 4 ions with the correct charges.

(Separate each with a "+" and place an "=>" after the 4th ion.)

4. On line 2...Write the correct molecular formula of the reactants by balancing the charges of the ions on line 3.

5. On line 2...Now write the correct formulas of the products. Remember the ions switch partners.

(the ratios may be different, pay attention to the charges.)

6. On line 2... Using the solubility rules, write the phase of each compound as a (subscript) after the formula.

(soluble=(aq), insoluble = (s), watch for the 5 exceptions=>LINK to Sol. Rules)

7. On line 3 and 4...Any solid liquid or gas can copied as in onto the lower lines.

(just write them as they appear on line 2, keep them on the right side of the arrow.)

8. On line 3... If a product is soluble (aq) in line 2, write the ions that make it up under it with "+" between them.

(just copy those ions from the left side of the arrow and put them on the right.)

(add (aq) to all ions...tedious step)

9. On line 2... Now you can balance the Molecular reaction

(keep yourself from balancing the reaction until the 2 reactions are finished.)

10. On line 3...You have to add coefficients to the ions and the compounds using the reaction form line 2.

(take the subscript for the ion (if it has one) and multiply it by the coefficient.)

(for the compound, just copy the coefficient from the previous reaction.)

11. On line 4... Ignore all spectator ions on line 3,  and place the remaining ions on line 4 with coefficients.

(Spectator ions appear the same on both sides of the reaction.)

(They don't actually participate in the reaction.)

(If you did this correctly the ions should for the product)

12. On line 4...Reduce the confidents to the lowest whole number ratio

PRACTICE PROBLEMS-

Write balanced formula unit, total ionic and net ionic equations for the following reactions. Assume all reactions occur in water or in contact with water.

 1. Silver nitrate and Rubidium chloride Overall Equation: AgNO3 (aq) + RbCl(aq) --> AgCl(s) + RbNO3 (aq) Total Ionic Equation: Ag+ (aq) + NO3- (aq) + Rb+(aq) + Cl-(aq) -> AgCl(s) + Rb+(aq) + NO3- (aq) Net Ionic Equation: Ag+ (aq) + Cl-(aq) -> AgCl(s) 2. mercury (I) nitrate and hydrochloric acid Overall Equation: Hg2(NO3)2 (aq) + 2 HCl (aq) --> Hg2Cl2 (s) + 2 HNO3 (aq) Total Ionic Equation: Hg22+(aq) + 2 NO3- (aq) + 2 H+(aq) + 2 Cl- (aq) --> Hg2Cl2 (s) + 2 H+ (aq) + 2 NO3-(aq) Net Ionic Equation: Hg2+(aq) + 2 Cl- (aq) --> Hg2Cl2 (s) 3. calcium chloride and sodium carbonate Overall Equation: CaCl2 (aq) + Na2CO3 (aq) -> 2 NaCl(aq) + CaCO3 (s) Total Ionic Equation: Ca2+(aq)+ 2 Cl- (aq) + 2 Na+ (aq)+ CO32- (aq) -> 2 Na+(aq) + 2 Cl-(aq) + CaCO3 (s) Net Ionic Equation: Ca2+(aq) + CO32- (aq) -> CaCO3 (s) 4. magnesium nitrate and calcium chloride Overall Equation: Mg(NO3)2 (aq) + CaCl2 (aq) -> Ca(NO3)2 (aq) + MgCl2 (aq) Total Ionic Equation: Mg2+ (aq) + 2 NO3- (aq) + Ca2+ (aq) + 2 Cl- (aq) --> Ca 2+(aq) + 2 NO3- (aq) + Mg2+(aq) + 2 Cl- (aq) Net Ionic Equation: No Reaction 5. potassium sulfate and barium chloride Overall Equation: K2SO4 (aq) + BaCl2 (aq) --> BaSO4 (s) + 2 KCl (aq) Total Ionic Equation: 2 K+ (aq)+ SO42- (aq) + Ba2+ (aq) + 2 Cl- (aq) --> BaSO4 (s) + 2 K+(aq)+ 2 Cl- (aq) Net Ionic Equation: SO42- (aq) + Ba2+ (aq) -> BaSO4 (s)

More problems- AP Chemistry

1) acetic acid + sodium hydroxide à

 1)     Formula Unit: HC2H3O2  +  NaOH  à  NaC2H3O2  + H2O Total Ionic: HC2H3O2     + Na+1  + OH-1  à  Na+1  +  C2H3O2-1  + H2O Weak acid Net Ionic: HC2H3O2    + OH-1  à   C2H3O2-1  + H2O

2) calcium hydroxide + hydrosulfuric acid à

 2)     Formula Unit: Ca(OH)2  +  H2S  à  CaS  +  2 H2O Total Ionic: Ca+2  +  2OH-1  +  2H +1  +  S-2  à    Ca+2  +  S-2  +  2 H2O Net Ionic: 2OH-1  +  2H +1  à    2 H2O  OH-1  +  H +1  à    H2O

3)Barium Nitrate + Potassium Carbonateà

 3)     Formula Unit: Ba(NO3)2  + K2CO3  à  BaCO3  +  2KNO3 Total Ionic: Ba+2  +  2NO3-1   +  2K +1  +  CO3-2  à  BaCO3  Insoluble   +  2K+1 +  2NO3-1 Net Ionic: Ba+2  +  CO3-2  à  BaCO3   Insoluble

4) lead (II) hydroxide  + carbonic acid  à