June 2004 Regents #41-50

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Questions

Answer Explanations
41 Using your knowledge of chemistry and the information in Reference Table H, which statement concerning propanone and water at 50°C is true?

(1) Propanone has a higher vapor pressure  and stronger intermolecular forces than water.
(2) Propanone has a higher vapor pressure and weaker intermolecular forces than water.
(3) Propanone has a lower vapor pressure  and stronger intermolecular forces than water.
(4) Propanone has a lower vapor pressure  and weaker intermolecular forces than water.

2 more vapor weaker intermolecular forces
42 A solution that is at equilibrium must be

(1) concentrated    (3) saturated
(2) dilute                (4) unsaturated

3 a solution is saturated when it is at equilibrium

dissolving and crystallizing are occurring at the same time

2 increasing surface area, concentration, temperature or catalyst increase reaction rate

this is not LeChaterlier because it is not at equilibrium 

1 Entropy 

gases>liquids>solids

45 Which pH indicates a basic solution?

(1) 1     (3) 7
(2) 5     (4) 12

 

 
4 Bases above 7

acids below 7

4 5 carbons the triple bond is on 2
4 use Reference tables
2 oxidation charge goes up

electrons on the more positive side

2 2.69d is the half live so it will be reduced by 1/2
50 As the elements of Group 1 on the Periodic Table are considered in order of increasing atomic radius, the ionization energy of each successive element generally

(1) decreases
(2) increases
(3) remains the same

1 going down group 1 it is easier to remove electrons as they are further from the nucleus

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