Simplified Explanation Dipole-dipole Interactions are stronger intermolecular forces than Dispersion forces occur between molecules that have permanent net dipoles (polar molecules), for example, dipole-dipole interactions occur between SCl2 molecules, PCl3 molecules and CH3Cl molecules. If the permanent net dipole within the polar molecules results from a covalent bond between a hydrogen atom and either fluorine, oxygen or nitrogen, the resulting intermolecular force is referred to as a hydrogen bond (see below). The partial positive charge on one molecule is electrostatically attracted to the partial negative charge on a neighbouring molecule. from-http://www.ausetute.com.au/intermof.html
from-http://www.ausetute.com.au/intermof.html