June 2009 Chemistry Regents #58-59

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Base your answers to questions 58 through 59 on the information below.

At a pressure of 101.3 kilopascals and a temperature of 373 K, heat is removed from a sample of water vapor, causing the sample to change from the gaseous phase to the liquid phase. This phase change is represented by the equation below.

H2O(g) ==> H2O(l) + heat

58 Explain, in terms of particle arrangement, why entropy decreases during this phase change. [1]

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The arrangement of the H2O molecules becomes more ordered as liquid water forms.

As a liquid, the movement of the particles is less random.

59 Determine the total amount of heat released by 5.00 grams of water vapor during this phase change. [1]

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ANSWER==>11 300 J

Q=mHv=5.00g (2260J/g)

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